A new sandwich polyoxometalate based on Keggin-type monolacunary polyoxotungstoborate anion, [Zr(α-BW11O39)2] |
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| Authors: | Yujuan Niu Bin Liu Ganglin Xue Huaiming Hu Feng Fu Jiwu Wang |
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| Affiliation: | aKey Laboratory of Synthetic and Natural Functional Molecule Chemistry (Ministry of Education), Shaanxi Key Laboratory of Physico-Inorganic Chemistry, Department of Chemistry, Northwest University, Xi’an 710069, China;bDepartment of Chemistry, Yanan University, Yan’an 716000, People’s Republic of China |
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| Abstract: | A new sandwich-type polyoxometalate based on Keggin-type monolacunary anion, [Zr(α-BW11O39)2]14− was synthesized and characterized by IR spectroscopy, UV electronic spectroscopy, cyclic voltammetry and single-crystal X-ray diffraction. This is the first report of crystal structure for the sandwich Keggin-type polyoxotungstoborate. |
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| Keywords: | Polyoxometalate Boron Zirconium Sandwich-type |
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