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新型酚醛树脂--苯并噁嗪树脂的研究进展
引用本文:向海,顾宜.新型酚醛树脂--苯并噁嗪树脂的研究进展[J].高分子材料科学与工程,2004,20(3):1-4,8.
作者姓名:向海  顾宜
作者单位:高分子材料工程国家重点实验室,四川大学高分子科学与工程学院,四川,成都,610065;高分子材料工程国家重点实验室,四川大学高分子科学与工程学院,四川,成都,610065
摘    要:摘要:综合论述了新型酚醛树脂——苯并噁嗪树脂的研究进展,主要侧重于从苯并噁嗪单体的合成及表征、苯并噁嗪聚合反应动力学与聚合反应机理、苯并噁嗪分子结构与性能的关系以及苯并噁嗪树脂的应用开发等方面进行论述。

关 键 词:苯并(哑心)嗪树脂  开环聚合  酚醛树脂
文章编号:1000-7555(2004)03-0001-04

RESEARCH DEVELOPMENTS OF A NEW CLASS PHENOLIC RESIN-BENXOZAZINE RESIN
XIANG Hai,GU Yi of Polymer Science and Engineering,Sichuan University,Chengdu ,China.RESEARCH DEVELOPMENTS OF A NEW CLASS PHENOLIC RESIN-BENXOZAZINE RESIN[J].Polymer Materials Science & Engineering,2004,20(3):1-4,8.
Authors:XIANG Hai  GU Yi of Polymer Science and Engineering  Sichuan University  Chengdu  China
Affiliation:XIANG Hai,GU Yi of Polymer Science and Engineering,Sichuan University,Chengdu 610065,China)
Abstract:A new class phenolic resin-benzoxazine resin has recently attracted a great deal of attention due to its versatile properties. Benzoxazine resin overcomes many of the traditional shortcomings of conventional phenolic resins, while retaining their benefits. The research developments of benzoxazine resin were reviewed in this paper. The developments in some aspects of synthesis and characterization of benzoxazine monomers, curing kinetic and polymerization mechanism of benzoxazine, the relationship of molecular structure and properties-including hydrogen-bonding properties, thermal and thermo-oxidative stability, photo-oxidative stability and volumetric change during the polymerization of benzoxazine, and application progress of benzoxazine resin were reviewed.
Keywords:benzoxazine resin  ring-open polymerization  phenolic resin
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