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A novel 3D 2-fold interpenetrated framework assembled via mixed bridging ligands |
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| Authors: | Li-Juan Chen Xiao-Yuan Wu Quan-Guo Zhai Zhen-Guo Zhao Qi-Sheng Zhang Can-Zhong Lu |
| Affiliation: | aState Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Science, Yangqiao West Road 155, Fuzhou, Fujian 350002, People’s Republic of China;bCollege of Chemistry and Materials Science, Fujian Normal University, Fuzhou, Fujian 350007, People’s Republic of China |
| Abstract: | Hydrothermal reaction of Cd(NO3)2, NaH2SIPA (5-sulfoisophthalalic acid monosodium salt) and pyrazine (Pz) resulted in a new polymeric complex {[Cd3(SIPA)2(pyrazine)(H2O)6] · 2H2O}n. X-ray structure analysis reveals that this complex features a 2-fold parallel interpenetrated 3D → 3D entanglement architecture, in which the single 3D network is constructed from {[Cd3(SIPA)2(H2O)6]}n 2D neutral layers interconnected by pyrazine ligands. |
| Keywords: | Coordination polymers 2-Fold interpenetrated Cadmium Mixed ligands |
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