| 氢化物发生原子荧光光谱法测定钨精矿中锑量 |
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| 引用本文： | 潘建忠,陈涛. 氢化物发生原子荧光光谱法测定钨精矿中锑量[J]. 中国钨业, 2010, 25(2): 43-45 |
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| 作者姓名： | 潘建忠 陈涛 |
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| 作者单位： | 赣州有色冶金研究所,江西,赣州,341000 |
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| 摘 要： | 本方法采用氢化物发生原子荧光光谱法测定钨精矿中锑量。经实验确定了测定锑量的最佳分析条件:试样经硫酸-硫酸铵分解,用柠檬酸在氨性介质中络合钨、铁、锰等,用抗坏血酸预还原五价的锑到三价,样品溶液在15%的酸度中,经流动注射-氢化物发生器与原子吸收分光光度计联用测定锑量。该方法具灵敏度高,准确性好,快速简便,干扰元素少等优点。检出下限可到0.001%锑量。
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| 关 键 词： | 氢化物发生 钨精矿 锑 |
Determination of Sb in Tungsten Concentrate by Hydride Generation Atomic Fluorescence Spectrometry |
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| PAN Jian-zhong,CHEN Tao. Determination of Sb in Tungsten Concentrate by Hydride Generation Atomic Fluorescence Spectrometry[J]. China Tungsten Industry, 2010, 25(2): 43-45 |
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| Authors: | PAN Jian-zhong CHEN Tao |
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| Affiliation: | PAN Jian-zhong,CHEN Tao(Ganzhou Nonferrous Metallurgy Institute,Ganzhou 341000,Jiangxi,China) |
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| Abstract: | The Sb amount in tungsten concentrate is determined by hydride generation atomic fluorescence spectrometry.The optimal analysis conditions is obtained by means of experiments:the sample is decomposed by sulfuric acid-ammonium sulfate,coordinated with tungsten,iron,manganese in ammonia medium using citric acid,then reduced pentavalent Sb to trivalent Sb by ascorbic acid.Sb amount in the 15 % acid solution is measured by the united equipments:flow injection-hydride generator-atomic absorption spectrophotomete... |
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| Keywords: | hydride generation atomic fluorescence spectrometry tungsten concentrate Sb |
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