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Sex-specific activity of (R)-(−)- and (S)- (+)-1,7-dioxaspiro[5.5]undecane,the major pheromone ofDacus oleae
Authors:G. Haniotakis  W. Francke  K. Mori  H. Redlich  V. Schurig
Affiliation:(1) Biology Department, N. R. C. "ldquo"Demokritos"rdquo" Aghia Paraskevi, Attiki, Greece;(2) Present address: Institute of Organic Chemistry and Biochemistry, University of Hamburg, F.R. Germany;(3) Present address: Department of Agricultural Chemistry, University of Tokyo, Japan
Abstract:1,7-Dioxaspiro[5.5]undecane (olean), the major component of the female sex attractant pheromone blend of the olive fruit flyDacus oleae (Gmelin) was shown to be released as a racemate. The response of males and females to pure (R)-(–) and (S)-(+)-enantiomers was tested under laboratory and field conditions. Males in laboratory and field tests responded only to (R)-(–)-olean, which functions as a sex attractant. Females responded only to (S)-(+)-olean in laboratory tests but not in the field. There are indications that the latter enantiomer fuctions as a short-range arrestant throughout the day and as an aphrodisiac in the process of mating.Diptera: Tephritidae.
Keywords:Dacus oleae  olive fruit fly  Diptera  Tephritidae  pheromones  enantiomers  sex attractants  sex-specific enantiomers
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