Sex-specific activity of (R)-(−)- and (S)- (+)-1,7-dioxaspiro[5.5]undecane,the major pheromone ofDacus oleae |
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Authors: | G. Haniotakis W. Francke K. Mori H. Redlich V. Schurig |
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Affiliation: | (1) Biology Department, N. R. C. Demokritos Aghia Paraskevi, Attiki, Greece;(2) Present address: Institute of Organic Chemistry and Biochemistry, University of Hamburg, F.R. Germany;(3) Present address: Department of Agricultural Chemistry, University of Tokyo, Japan |
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Abstract: | 1,7-Dioxaspiro[5.5]undecane (olean), the major component of the female sex attractant pheromone blend of the olive fruit flyDacus oleae (Gmelin) was shown to be released as a racemate. The response of males and females to pure (R)-(–) and (S)-(+)-enantiomers was tested under laboratory and field conditions. Males in laboratory and field tests responded only to (R)-(–)-olean, which functions as a sex attractant. Females responded only to (S)-(+)-olean in laboratory tests but not in the field. There are indications that the latter enantiomer fuctions as a short-range arrestant throughout the day and as an aphrodisiac in the process of mating.Diptera: Tephritidae. |
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Keywords: | Dacus oleae olive fruit fly Diptera Tephritidae pheromones enantiomers sex attractants sex-specific enantiomers |
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