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脉冲电晕净化NO的化学动力学耦合流体动力学数值模拟
引用本文:侯文慧,张海茹,范朋慧,杨蒙,仲兆平,杨宏曼. 脉冲电晕净化NO的化学动力学耦合流体动力学数值模拟[J]. 燃烧科学与技术, 2011, 17(4): 368-374
作者姓名:侯文慧  张海茹  范朋慧  杨蒙  仲兆平  杨宏曼
作者单位:1. 南京师范大学能源与机械工程学院,南京,210042
2. 东南大学能源与环境学院,南京,210096
基金项目:国家自然科学基金资助项目
摘    要:探讨了利用CHEMKIN4.1与FLUENT6.2软件耦合预测脉冲电晕放电条件下NO的净化过程.利用脉冲放电时间平均集合模型,计算出N2/O2在高能电子撞击下的离解速率常数,提出一套NO/O2/N2体系反应机理.结合CHEMKIN的敏感性分析方法对反应机理进行了分析,预测了活性自由基元(N、O)体积分数的变化趋势,获得...

关 键 词:NO脱除  化学动力学  耦合  计算流体力学  等离子

Numerical Simulation on Removal of NO Under Pulse Corona Discharge by Chemical Kinetic Coupled with Computation Fluid Dynamics
HOU Wen-hui,ZHANG Hai-ru,FAN Peng-hui,YANG Meng,ZHONG Zhao-ping,YANG Hong-min. Numerical Simulation on Removal of NO Under Pulse Corona Discharge by Chemical Kinetic Coupled with Computation Fluid Dynamics[J]. Journal of Combustion Science and Technology, 2011, 17(4): 368-374
Authors:HOU Wen-hui  ZHANG Hai-ru  FAN Peng-hui  YANG Meng  ZHONG Zhao-ping  YANG Hong-min
Affiliation:HOU Wen-hui1,ZHANG Hai-ru1,FAN Peng-hui1,YANG Meng1,ZHONG Zhao-ping2,YANG Hong-min1(1.School of Energy and Mechanical Engineering,Nanjing Normal University,Nanjing 210042,China,2.School of Energy and Environment,Southeast University,Nanjing 210096,China)
Abstract:The numerical simulation for the removal of NO under pulse corona discharge using CHEMKIN4.1 cou-pled with FLUENT6.2 software was discussed.The reaction rate constant of the ionization of N2/O2 by electron-impact dissociation was calculated by the lumped kinetic model of pulse corona discharge,and a kinetic model in the system of NO/O2/N2 under pulse corona discharge was obtained.The kinetic mechanism was analyzed by the sensitiv-ity analysis method in CHEMKIN.The concentrations of free radicals(N,O)were pr...
Keywords:NO removal  chemical kinetic  coupling  computation fluid dynamics(CFD)  plasma  
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