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稀四氟化碳气体混合物传递性质的确定(英文)
作者姓名:Mohammad Mehdi Papari  Jalil Moghadasi  Soodabeh Nikmanesh  Mahmood Reza Dehghan
作者单位:1. Department of Chemistry, Shiraz University of Technology, Shiraz 71555-313, Iran;2. Department of Chemistry, Shiraz University, Shiraz 71454, Iran
摘    要:In our previous work, we calculated transport properties of pure gaseous polyatomic carbon tetrafluoride (CF4) and five equimolar binary gas mixtures of CF4 with noble gases through inversion technique. The present work is a continuation of our studies on determining the transport properties of binary gas mixtures CF4 with some gases including three diatomic molecules CO, N2, and O2, a linear polyatomic CO2, and two non-linear polyatomic molecules SF6 and CH4. The Chapman-Enskog and Vesovic-Wakeham methods as well as inversion procedure are used to determine the viscosities, diffusivities, and thermal conductivities, which deviates from the literature values within 1%, 4%, and 5%, respectively.

关 键 词:principle  of  corresponding  states  inversion  method  kinetic  theory  of  gases  diffusivity  thermal  conductivity  viscosity  transport  properties  
收稿时间:2009-8-4
修稿时间:2009-8-4  

Determination of transport properties for dilute gas mixtures containing carbon tetrafluoride
Mohammad Mehdi Papari,Jalil Moghadasi,Soodabeh Nikmanesh,Mahmood Reza Dehghan.Determination of transport properties for dilute gas mixtures containing carbon tetrafluoride[J].Chinese Journal of Chemical Engineering,2010,18(2):297-305.
Authors:M M Papari  J Moghadasi  S Nikmanesh  M R Dehghan
Affiliation:1. Department of Chemistry, Shiraz University of Technology, Shiraz 71555-313, Iran;2. Department of Chemistry, Shiraz University, Shiraz 71454, Iran
Abstract:In our previous work,we calculated transport Fpropetiens of pure gaseous polyatomic carbon tetra fluoride(CF4)and five equimolar binary gas mixtures of CF4 with noble gases through inversion technique.The present work is a continuation of our studies on determining the transport properties of binary gas mixtures CF4with some gases including three diatomic molecules CO,N2,and O2,a linear polyatomic CO2,and two non-linear polyatomic molecules SF6 and CH4.The Chapman-Enskog and Vesovic-Wakeham methods as well as inversion procedure are used to determine the viscosities,diffusivities,and thermal conductivities,which deviates from the literature values within 1%,4%,and 5%,respectively.
Keywords:principle of corresponding states  inversion method  kinetic theory of gases  diffusivity  thermal con ductivity  viscosity  transport properties
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