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有机掺杂长余辉发光材料的研究进展
引用本文:王豪,宋亚坤,刘军辉,李想,汪天洋,高嘉屿. 有机掺杂长余辉发光材料的研究进展[J]. 精细化工, 2023, 40(9)
作者姓名:王豪  宋亚坤  刘军辉  李想  汪天洋  高嘉屿
作者单位:河南科技大学 化学化工学院,河南科技大学 化学化工学院,河南科技大学 化学化工学院,河南科技大学 化学化工学院,天津市分子光电重点实验室,河南科技大学 化学化工学院
基金项目:国家自然科学基金(21908043);河南省科技攻关项目(232102230148);河南省科技攻关项目(232102240006)
摘    要:纯有机长余辉发光材料具有制备方法简单、成本低廉、可柔性化、环境友好等优点,被广泛应用于防伪、信息保密、生物成像等领域。其中,基于掺杂体系的纯有机长余辉发光材料,可通过调控主客体之间的配位关系,实现长余辉时间和颜色的可调性,并可在室温下制备出性能优异的长余辉发光材料,是目前有机长余辉发光材料研究的热点。本文分别从小分子基质体系、大分子基质体系、聚合物体系等方面综述了该领域的研究进展,介绍了相关材料在信息加密与防伪、生物成像、柔性纤维薄膜等领域的应用。最后,指出了目前有机掺杂长余辉发光材料研究中还存在的一些问题,并展望了其发展前景。

关 键 词:有机长余辉材料  掺杂  室温磷光  非辐射跃迁  研究进展
收稿时间:2023-03-24
修稿时间:2023-05-17

Recent development of organic-doped materials with long-persistent luminescence
WANG Hao,SONG Ya-kun,LIU Jun-hui,LI Xiang,WANG Tian-yang and GAO Jia-yu. Recent development of organic-doped materials with long-persistent luminescence[J]. Fine Chemicals, 2023, 40(9)
Authors:WANG Hao  SONG Ya-kun  LIU Jun-hui  LI Xiang  WANG Tian-yang  GAO Jia-yu
Affiliation:College of Chemical Engineering and Pharmacy,Henan University of Science and Technology,Luoyang,College of Chemical Engineering and Pharmacy,Henan University of Science and Technology,Luoyang,College of Chemical Engineering and Pharmacy,Henan University of Science and Technology,Luoyang,College of Chemical Engineering and Pharmacy,Henan University of Science and Technology,Luoyang,Tianjin Key Laboratory of Molecular Optoeletronic Science,Department of Chemistry,School of Science,College of Chemical Engineering and Pharmacy,Henan University of Science and Technology,Luoyang
Abstract:Purely organic long-persistent luminescent materials are widely used in the fields of anti-counterfeiting, information security, biological imaging, and other applications due to their benefits of ease of synthesis, low cost, flexibility, and environmental friendliness. Among them, organic long-persistent luminescence materials based on doping systems have become a current focus of research for long-persistent luminescence materials because they enable the adjustment of luminescent time and color by controlling the coordination relationship between host and guest. This article reviews the developments in the disciplines of micromolecular, macromolecular, and polymer matrix research, as well as the uses of related materials in fields such as information security and counterfeit prevention, biological imaging, flexible fiber film, and others. Finally, some problems existing in the research area are pointed out, and their development prospects are prospected.
Keywords:organic long-persistent luminescence materials   doping   room temperature phosphorescence   non-radiative transition   research progress
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