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分光光度法快速测定复合肥中有效磷含量的测量不确定度评定
引用本文:张辰,席武军.分光光度法快速测定复合肥中有效磷含量的测量不确定度评定[J].化肥工业,2012,39(3):33-36.
作者姓名:张辰  席武军
作者单位:1. 营口市产品质量监督检验所 辽宁营口 115000
2. 营口市第二技工学校 辽宁营口 115000
摘    要:分析了分光光度法快速测定复合肥中有效磷含量的测量不确定度的主要来源,对各不确定度分量进行了评定,求得合成标准不确定度和扩展不确定度分别为0.21%和0.42%。不确定度分析与评定结果表明:影响分光光度法快速测定复合肥中有效磷含量的测量不确定度的主要因素是标准工作曲线拟合引入的不确定度,加强这方面的控制可提高测量结果的准确性。

关 键 词:分光光度法  有效磷  不确定度  评定

Assessment of Uncertainty in Rapid Determination of Available Phosphate Content in Compound Fertilizers by Spectrophotography
Zhang Chen , Xi Wujun.Assessment of Uncertainty in Rapid Determination of Available Phosphate Content in Compound Fertilizers by Spectrophotography[J].Journal of the Chemical Fertilizer Industry,2012,39(3):33-36.
Authors:Zhang Chen  Xi Wujun
Affiliation:1.Yingkou Product Quality Supervision and Inspection Institute Liaoning Yingkou 115000; 2.Yingkou Second Technical School Liaoning Yingkou 115000)
Abstract:The main sources of uncertainty are analyzed in rapid determination of available phosphate content in compound fertilizers by spectrophotography,an assessment is made of various uncertainty components,and it is found that the composition standard uncertainty and extension uncertainty are respectively 0.21% and 0.42%.The results of uncertainty analysis and assessment show that the main factor affecting uncertainty in determination is the uncertainty introduced into the standard working cure fitting,so strengthening the control in this respect will improve the precision of the determination results.
Keywords:spectrophotography available phosphate uncertainty assessment
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