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Magnesium octa[(4′-benzo-15-crown-5)oxy]phthalocyaninate in water micellar solutions of sodium deoxycholate |
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| Authors: | N F Gol’dshleger A S Lobach V Yu Gak I P Kalashnikova V E Baulin A Yu Tsivadze |
| Affiliation: | 1. Institute of the Problems of Chemical Physics, Russian Academy of Sciences, pr. Akademika Semenova 1, Chernogolovka, Moscow oblast, 142432, Russia 2. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia 3. Institute of Physiologically Active Substances, Russian Academy of Sciences, Severnyi proezd 1, Chernogolovka, Moscow oblast, 142432, Russia |
| Abstract: | Aggregation of magnesium octa-(4′-benzo-15-crown-5)oxy]phthalocyaninate (Mgcr8Pc) in solutions of biocompatible anionic surfactant, sodium deoxycholate (SDC), was studied. It was shown using the electron absorption spectra that formation of Mgcr8Pc monomers in micellar solutions of SDC is affected by both increased surfactant concentration and by changes in the ionic strength of solution after sodium chloride is added. The effect of the chemical structure of biocompatible anionic surfactant on monomerization of crown-containing phthalocyanines was identified; this fact opens new possibilities for using this family of compounds for fluorescent diagnosis and photodynamic therapy. |
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