| 双-2-噁唑啉化合物对PET的改性作用研究 |
| |
| 引用本文： | 石永刚,潘恩黎,陈瑞珠,张云灿.双-2-噁唑啉化合物对PET的改性作用研究[J].合成树脂及塑料,1995(2). |
| |
| 作者姓名： | 石永刚 潘恩黎 陈瑞珠 张云灿 |
| |
| 作者单位： | 南京化工学院，南京化工学院，南京化工学院，南京化工学院 江苏，210009，江苏，210009，江苏，210009，江苏，210009 |
| |
| 摘 要： | 用挤出机熔融共混法,比较了2,2′-双(2-噁唑啉),1,4-双(2-噁唑啉)苯和1,3-双(2-噁唑啉)苯3种双噁唑啉化合物与PET端羧基进行偶联反应和封端反应的程度和差别;并考查双噁唑啉助剂加入量,挤出温度与时间,后热处理对扩链效果的影响,以及研究扩链后PET的热失重、水解稳定性,力学性能及~(13)C～NMR分析。结果表明,经噁唑啉化合物扩链的PET增进了热稳定性和耐水解性,提高玻纤增强PET的力学性能。
|
| 关 键 词： | 聚对苯二甲酸乙二醇酯 双-2-噁唑啉 改性 扩链 |
Study on Modifying Effect of Bisoxazolines on PET |
| |
| Shi Yonggang,Pan Enli,Chen Ruizhu and Zhang Yuncan.Study on Modifying Effect of Bisoxazolines on PET[J].China Synthetic Resin and Plastics,1995(2). |
| |
| Authors: | Shi Yonggang Pan Enli Chen Ruizhu and Zhang Yuncan |
| |
| Affiliation: | Nanjing Institute of Chemical Technology |
| |
| Abstract: | The efficiency and difference in proceeding coupled and blocked reaction of PET with 2,2-bis (2-oxazoline) or 1,4 -bis (2-oxazolinyl) benzene and 1,3-bis (2-oxazolinyl) benzene were evaluated during meltblended by an extruder . The influence of added amount of bisoxazoline . extruding temperature and time , as well as post-heat treatment on chain - extending efficiency for PET were examined .Some properties of chain-extended PET , such as loss of weight by thermogravimetric analysis , hydrolytic stability . the mechanical properties of chain-extended PET/GF reinforced composites and characterization of 13C-NMR , were investigated . The results showed that above mentioned properties for chain-extended PET were considerably improved. |
| |
| Keywords: | PET : bis-2-oxazoline modification : chain extension |
| 本文献已被 CNKI 等数据库收录！ |
|
