| 接枝环境下丙烯酸丁酯自由基聚合反应动力学 |
| |
| 引用本文： | 许国强,林恒,黄雪红. 接枝环境下丙烯酸丁酯自由基聚合反应动力学[J]. 石油化工, 1998, 0(7) |
| |
| 作者姓名： | 许国强 林恒 黄雪红 |
| |
| 作者单位： | 福建师范大学高分子研究所 |
| |
| 摘 要： | 用膨胀计法研究了丙烯酸正丁酯在接枝体系中的聚合反应动力学。发现被接枝物ＳＢＳ浓度低于某一数值时，聚合反应速率与ＳＢＳ浓度无关。还测得在ＳＢＳ浓度不大于０．２７ｍｏｌ／Ｌ时，引发剂浓度、单体浓度对反应速率的级数分别为０．６和１．８３。
|
| 关 键 词： | 丙烯酸正丁酯 苯乙烯－丁二烯嵌段共聚物 接枝共聚合 聚合反应动力学 |
Kinetics of Radical Polymerization of Butyl Acrylate in the Presence of SBS in Solution |
| |
| Abstract: | he kinetics of free radical polymerization of butyl acrylate (BA) in the presence of thermoplastic elastomer (SBS) has been studied dilatometrically in toluene at 90 ℃ ,with benzoyl peroxide (BPO) as initiatorThe results indicated that the kinetics of BA polymerization was different from the classic kinetics of polymerizationAn initiator order of 06 and a monomer order of 183 were obtained for this systemsThe effects of the concentration of SBS were also studiedThe results showed the polyme rization rate was not changed when the concentration of SBS was not in excess of 027 mol/L |
| |
| Keywords: | butyl acrylate thermoplastic elastomer graft copolymerization kinetics of radical polymerization |
| 本文献已被 CNKI 等数据库收录！ |
