Effect of K0.5Na0.5NbO3 filling particles on the charge carrier trap distribution of polyimide films |
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| Authors: | Jiaqi Lin Zhibin Xie Wenlong Yang Panpan Zhang Ying Liu Hui Lin Xiaokang Li |
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| Affiliation: | 1. Department of Applied Science, Harbin University of Science and Technology, Harbin, China;2. Key Laboratory of Education of Harbin University of Science and Technology, Harbin, China |
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| Abstract: | Polyimide (PI) films filled with K0.5Na0.5NbO3 (KNN50) particles at different weight 0, 5, 10, and 15 wt % had been prepared by in‐situ dispersion polymerization process. The thermally stimulated current (TSDC) method was used to investigate the charge carrier trap levels and their distribution of the composite films. The TSDC spectra show that pure film has  ‐peaks and  ‐peak, but the composite films only have  ‐peaks and an extraordinary peak at high temperature region. The trap parameters were calculated by an approximate model, and the results indicate that charge released of the shallow traps show a nonlinear behavior. The trap energies decrease from 0.879–0.968 eV to 0.549–0.839 eV with the increase of the KNN50 content. The surface and interface between KNN50 and PI matrix was considered to the variation of the trap levels. The extraordinary peak of the composite films was correlated with the phase transition of the KNN50 particles. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 39828. |
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| Keywords: | composites films polyimides |
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