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烷烃的定容喷射自燃研究
引用本文:王俊 杨鹤 宋海清 田华宇 王鹏飞. 烷烃的定容喷射自燃研究[J]. 中国炼油与石油化工, 2019, 21(1): 71-79
作者姓名:王俊 杨鹤 宋海清 田华宇 王鹏飞
作者单位:1. 中国石油化工股份有限公司石油化工科学研究院;2. 中国石化石油化工科学研究院;
摘    要:In this study, spray auto-ignition experiments were carried out on a constant volume combustion chamber for some alkanes like n-paraffins with different chain length, cyclohexane, n-butyl cyclohexane, and isooctane. The auto-ignition qualities of n-heptane, isooctane and n-decane under different initial chamber temperature were investigated in details. Results showed that n-paraffins’ reaction activity was relatively high. Meanwhile, the auto-ignition characteristics differed significantly with different molecular structure. Adding n-decane with various volume fractions to Standard Blended Fuel and product gasoline would improve the fuel reaction activity to varying degrees. At last, the functional groups effects were formulated to simulate the relationship between molecular topology and auto-ignition quality.

关 键 词:喷射自燃   反应活性   官能团   烷烃  
收稿时间:2018-09-03
修稿时间:2018-09-26

Constant Volume Spray Auto-ignition Study of Alkanes
Wang Jun,Yang He,Song Haiqing,Tian Huayu,Wang Pengfei. Constant Volume Spray Auto-ignition Study of Alkanes[J]. China Petroleum Processing and Petrochemical Technology, 2019, 21(1): 71-79
Authors:Wang Jun  Yang He  Song Haiqing  Tian Huayu  Wang Pengfei
Affiliation:1. SINOPEC Research Institute of Petroleum Processing;2. Research Institue of Petroleum Processing, SINOPEC;3. ;4. SINOPEC Reascher Institute of Petroleum Processing;
Abstract:Spray auto-ignition experiments were carried out in a constant volume combustion chamber for some pure alkanes(n-paraffins with different chain length, cyclohexane, n-butyl cyclohexane, and isooctane) and blends of n-decane with Standard Blended Fuel(isooctane/n-heptane) and product gasoline. Test results showed that the reaction activity of n-paraffins was relatively high. Meanwhile, the auto-ignition characteristics differed significantly with the molecular structures of alkanes. Adding different volume fractions of n-decane to Standard Blended Fuel and product gasoline could improve the fuel reaction activity at varying degree. Finally, functional groups effects were used to simulate the relationship between the molecular topology and the auto-ignition quality.
Keywords:spray auto-ignition   reaction activity   functional group   alkane  
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