| Hydrothermal Synthesis and Characterization of a Novel Organic Inorganic Hybrid Compound [Co（dien）2]（dienH3）（H3O）7[P2Mo5O23]2·14H2O |
| |
| 引用本文： | ZHAO Weifeng ZHANG Lianmeng JIN Surong. Hydrothermal Synthesis and Characterization of a Novel Organic Inorganic Hybrid Compound [Co（dien）2]（dienH3）（H3O）7[P2Mo5O23]2·14H2O[J]. 武汉理工大学学报(材料科学英文版), 2007, 22(1): 120-121. DOI: 10.1007/s11595-005-1120-4 |
| |
| 作者姓名： | ZHAO Weifeng ZHANG Lianmeng JIN Surong |
| |
| 作者单位： | ZHAO Weifeng（State Key Laboratory of Advanced Technology for Materials Synthesis and Processing,Wuhan University of Technology,Wuhan,430070,China） ;ZHANG Lianmeng（State Key Laboratory of Advanced Technology for Materials Synthesis and Processing,Wuhan University of Technology,Wuhan,430070,China） ;JIN Surong（State Key Laboratory of Advanced Technology for Materials Synthesis and Processing,Wuhan University of Technology,Wuhan,430070,China） ; |
| |
| 基金项目： | Funded by the Natural Science Foundation of Hubei Province(No. 2003ABA085) and Key Laboratory for Silicate Materials Science and Engineering (Wuhan University of Technology),Ministry of Education (No.2003-SJSJJ-15) |
| |
| 摘 要： | A new compound,[Co（dien）2]（dienH3）（H3O）7[P2Mo5O23]2·14H2O, has been hydrothermallly synthesized by using Na2MoO4,CoCl2, H3PO4 and dien, and structurally characterized by elemental analysis, X-ray powder diffraction analysis, SEM, IR and TG analysis. The results show that the compound is composed of a polyanion [P2Mo5O23]2^12, complex [Co（dien）2]^2＋ cation, protonated [dienH3]^3＋ , and forteen crystallization water molecule.
|
| 关 键 词： | 有机无机杂化化合物 杂多化合物 水热合成 表征 氧配位聚合物 钴 钼 |
| 收稿时间： | 2005-06-18 |
| 修稿时间： | 2006-09-21 |
Hydrothermal synthesis and characterization of a novel organic inorganic hybrid compound [Co(dien)2] (dienH3)(H3O)7[P2Mo5O23]2·14H2O |
| |
| Zhao Weifeng , Zhang Lianmeng and Jin Surong. Hydrothermal synthesis and characterization of a novel organic inorganic hybrid compound [Co(dien)2] (dienH3)(H3O)7[P2Mo5O23]2·14H2O[J]. Journal of Wuhan University of Technology. Materials Science Edition, 2007, 22(1): 120-121. DOI: 10.1007/s11595-005-1120-4 |
| |
| Authors: | Zhao Weifeng Zhang Lianmeng Jin Surong |
| |
| Affiliation: | (1) State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan, 430070, China |
| |
| Abstract: | A new compound, [Co(dien)2](dienH3)(H3O)7[P2Mo5O23]2·14H2O, has been hydrothermallly synthesized by using Na2MoO4, CoCl2, H3PO4 and dien, and structurally characterized by elemental analysis, X-ray powder diffraction analysis, SEM, IR and TG analysis. The results show that the compound is composed of a polyanion [P2Mo5O23]2 12− complex [Co(dien)2]2+ cation, protonated [dienH3]3+, and forteen crystallization water molecule. Funded by the Natural Science Foundation of Hubei Province (No. 2003ABA085) and Key Laboratory for Silicate Materials Science and Engineering (Wuhan University of Technology), Ministry of Education (No.2003-SJSJJ-15) |
| |
| Keywords: | hydrothermal synthesis heteropoly compound organic-inorganic hybrid compound |
| 本文献已被 维普 SpringerLink 等数据库收录！ |
|
