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Statistical assessment of gas/liquid mass transfer in slurry-phase propylene polymerization process
Authors:J Li  Z Tekie  A Mohammad  B I Morsi
Abstract:A statistical approach was developed to investigate the effects of pressure, temperature, mixing speed and solid concentration on kLa for gaseous hydrogen, ethylene, and propylene in liquid n-hexane containing solid polypropylene powder in a 4-litre agitated reactor. The solubilities of the gases appeared to follow Henry's Law. Statistical correlations to predict kLa were proposed and response surfaces were constructed. kLa values appeared to reach a maximum around 15 mass% and sharply decrease above 30 mass%. The effects of pressure and temperature on kLa were found to depend on the gas-liquid system and operating conditions used.
Keywords:mass transfer  slurry reactor  polymerization  experimental design
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