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羟醛缩合催化剂研究进展
引用本文:谭露璐,钱君律,伍艳辉. 羟醛缩合催化剂研究进展[J]. 化学工业与工程, 2006, 23(1): 70-74
作者姓名:谭露璐  钱君律  伍艳辉
作者单位:同济大学化学系,上海,200092;同济大学化学系,上海,200092;同济大学化学系,上海,200092
摘    要:羟醛缩合可以形成新的碳-碳键,增长碳链,是一类重要的有机反应。反应过程中同时存在许多副反应,导致反应选择性的降低,选择合适的催化剂对此类反应十分关键。本文根据活性中心的不同,对酸性、碱性和酸-碱两性三类不同的催化剂进行了论述,分析了羟醛缩合反应催化剂今后的发展方向。

关 键 词:羟醛缩合  催化剂  活性中心  催化机理
文章编号:1004-9533(2006)01-0070-05
收稿时间:2005-01-26
修稿时间:2005-01-26

Advances in Catalysts of Aldol Condensation
TAN Lu-lu,QIAN Jun-lü,WU Yan-hui. Advances in Catalysts of Aldol Condensation[J]. Chemical Industry and Engineering, 2006, 23(1): 70-74
Authors:TAN Lu-lu  QIAN Jun-lü  WU Yan-hui
Affiliation:Department of Chemistry., Tongii University, Shanghai 200092, China
Abstract:Aldol condensation is an important organic reaction which leads to the formation of new C-C bond.The desired yield can not been easily achieved because this reaction is always accompanied by a series of side reactions.It's predominant to select a proper catalyst in order to industrialize this reaction.In this paper,three kinds of catalysts are introduced and discussed according to the acid or base active site.The prospect of the catalysts for aldol condensation is also been put forward.
Keywords:aldol condensation  catalyst  active site  catalysis mechanism  
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