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Effect of Regime of Addition of Initiator on TEMPO-Mediated Polymerization of Styrene |
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| Authors: | F?Díaz-Camacho S?López-Morales E?Vivaldo-Lima E?Saldívar-Guerra R?Vera-Graziano |
| Affiliation: | (1) Instituto de Investigaciones en Materiales, Mexico;(2) Facultad de Química, Universidad Nacional Autónoma de México, Circuito Exterior s/n, CU, Coyoacán, México D.F., 04510, Mexico;(3) Centro de Investigación en Química Aplicada, Blvd. Enrique Reyna 140, Saltillo, Coahuila, 25100, Mexico |
| Abstract: | Summary Investigation of the TEMPO-mediated polymerization of styrene at different regimes of addition of AIBN initiator showed that the course of the polymerization could be changed dramatically by a mode of the initiator addition without using any other additives. A very significant acceleration of the polymerization was reached at a specific regime without broadening the polydispersity of the resulting polymer. |
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