| 吡啶及其衍生物催化合成进展及应用前景 |
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| 引用本文： | 周焕文,于世钧,徐杰,朱丹. 吡啶及其衍生物催化合成进展及应用前景[J]. 工业催化, 2001, 9(3): 26-32 |
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| 作者姓名： | 周焕文 于世钧 徐杰 朱丹 |
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| 作者单位： | 1.中科院大连化学物理研究所,辽宁 大连 116012;2.辽宁师范大学化学系,辽宁 大连 116029 |
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| 摘 要： | 吡啶及其衍生物广泛应用于医药。农药。橡胶和染料的生产。本文综述了目前世界工业上用Tl,Pd,Pb,Cd等金属改进的沸石分子筛(如ZSM-5。β。Y等)作为催化剂,以醛。酮。醇。不饱和烃或芳胺与氨反应来催化合成吡啶及其衍生物的概况,以及采用甲醇和空气进行催化剂再生的新方法。
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| 关 键 词： | 吡啶及其衍生物 催化合成 改性沸石催化剂 ZSM-5 再生 |
| 文章编号： | 1008-1143(2001)03-0026-07 |
| 修稿时间： | 2000-08-03 |
Development of and application prospect for the methods for catalytic synthesis of pyridine and its derivatives |
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| ZHOU Huan wen ,YU Shi jun ,XU Jie ,ZHU Dan. Development of and application prospect for the methods for catalytic synthesis of pyridine and its derivatives[J]. Industrial Catalysis, 2001, 9(3): 26-32 |
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| Authors: | ZHOU Huan wen YU Shi jun XU Jie ZHU Dan |
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| Affiliation: | 1.Dalian Research Institute of Chemical Physics,Chinese Academy of Sciences,;Liaoning Dalian 116012,China;2.Chemistry Department,Liaoning Normal University,Liaoning Dalian 116029,China |
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| Abstract: | Pyridine and its derivatives are widely used in pharmaceutical,insecticide,rubber and dyestuff industry.Pyridine and its derivatives are manufactured from aldehydes,ketones,alcohols and unsaturated hydrocarbons or reaction between arylamines and ammonia over zeolite catalyst(such as ZSM-5,β and Y zeolite)promoted by Tl,Pd,Pb and Cd.A new regeneration method using methanol and air is also described. |
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| Keywords: | Pyridine and its derivatives modified zeolite catalyst catalytic synthesis regeneration |
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