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Co基催化剂用于费托蜡合成的研究
引用本文:张建雨,李祥,许剑杰,刘莲,沈春明,牛效沛,冯彤彤,冯强强. Co基催化剂用于费托蜡合成的研究[J]. 广州化工, 2009, 37(9): 123-125
作者姓名:张建雨  李祥  许剑杰  刘莲  沈春明  牛效沛  冯彤彤  冯强强
作者单位:华东理工大学资源与环境工程学院,上海,200237;上海五将化工科技有限公司,上海,200437
摘    要:以SiO2为载体,分别制备了添加Zr,Mn及Ce助剂的三种钴基催化剂。通过反应装置上评价,含Zr助剂的催化剂反应活性和蜡产率最高。考察了不同温度,压力,空速对添加Zr助剂的催化剂催化性能的影响。结果表明:随着温度升高,蜡产率先增加后减少;高压和低空速适合蜡的生成。

关 键 词:费托合成蜡  钴基催化剂  蜡产率

Study on Synthesis of Fischer-tropsch Wax by Cobalt-based Catalysts
ZHANG Jian-yu,LI Xiang,XU Jian-jie,LIU Lian,SHEN Chun-ming,NIU Xiao-pei,FENG Tong-tong,FENG Qiang-qiang. Study on Synthesis of Fischer-tropsch Wax by Cobalt-based Catalysts[J]. GuangZhou Chemical Industry and Technology, 2009, 37(9): 123-125
Authors:ZHANG Jian-yu  LI Xiang  XU Jian-jie  LIU Lian  SHEN Chun-ming  NIU Xiao-pei  FENG Tong-tong  FENG Qiang-qiang
Affiliation:1 College of Resource and Environmental Engineering;East China University of Science and Technology;Shanghai 200237;2 Shanghai Wujiang Chemical Technology Co.;Ltd.;China
Abstract:SiO_2 was used as supporters to prepare three Cobalt -based catalysts which were modified with Zr,Mn and Ce promoter.After experimenting on fix - bed reactor system,it was found that the catalysts with Zr promoter had best activity and highest yield of Fischer - Tropsch wax.The catalytic perfomance of Co/Zr/SiO_2 catalysts was investigated in different operation conditions including temprature,pressure and gas hourly space velocity.The results showed that the yield of Fischer - Tropsch wax was high when exp...
Keywords:Fischer-Tropsch  Cobalt-based catalysts  the yield of wax  
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