高能电子束辐射对碳纤维表面结构的影响

利用激光拉曼光谱（Raman Spectroscopy）、X射线光电子能谱（XPS）、原子力显微镜（AFM）和X射线衍射（XRD）对高能电子束辐射前后的表面结构进行分析，结果表明，随着剂量的增加，碳纤维表面石墨微晶尺寸增大。碳原子在高能电子束的作用下离位，使表面棱角超于圆滑，当剂量较大时，处于石墨片层边缘的活性碳原子重新增多。碳纤维表面极性官能团受辐射介质产生的活性种的影响，同时在高能电子束辐射下激活，发生自淬灭反应和解离反应，前者占优势时，高价态的C＝O增多，反之，C－O基团增多。在试验范围内，高能电子束对碳纤维的晶型结构无影响。

EFFECT OF EB IRRADIATION ON THE STRUCTURES OF CARBON FIBER SURFACE

The object of this work is to investigate the effect of EB irradiation on carbon fiber surface. The laser Raman spectroscopy, X ray photoelectron spectroscopy (XPS), atomic force microscopy (AFM) and X ray diffraction were used to observe the surface changes including an enhancement in oxygen and nitrogen containing groups, smooth degree of carbon fiber surface and in size of graphite crystal layers. It showed that polar groups on carbon-fiber surface were influenced by the active species creacted in the media during EB irradiation. The self-quenching reaction or disengage reaction took place in activated groups. The group C=O was increased in the former reaction, on the other hand, the group C-O in the latter reaction. The crystal structure of the bulk carbon fiber was not effected by EB irradiation.