| EU-1/ZSM-5复合分子筛的合成与表征 |
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| 引用本文： | 闫萍,马波,张喜文,张志智.EU-1/ZSM-5复合分子筛的合成与表征[J].石油炼制与化工,2011,42(6):17-22. |
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| 作者姓名： | 闫萍 马波 张喜文 张志智 |
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| 作者单位： | 1. 辽宁石油化工大学;抚顺石油化工研究院;2. 抚顺石油化工研究院; |
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| 基金项目： | 中国石油化工股份有限公司资助项目 |
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| 摘 要： | 以四丙基氢氧化铵（TPAOH）和四丙基溴化铵（TPABr）为模板剂、 EU-1为铝源，水热晶化合成EU-1/ZSM-5复合分子筛。采用XRD，SEM-EDS，N2吸附-脱附及FT-IR等手段对合成样品进行表征。结果表明，所合成的EU-1/ZSM-5复合分子筛具有与EU-1分子筛及ZSM-5分子筛混合物相同的XRD图谱，但红外谱图的谱峰均向高波数方向偏移，并产生明显的次级介孔结构；在形貌上，复合分子筛中EU-1相周边规整附晶生长着ZSM-5分子筛的纳米颗粒。EU-1/ZSM-5复合分子筛的合成条件为m (EU-1)/m (SiO2)=1.1~1.4，n (OH-)/n (SiO2)=0.07~0.15，n (TPAOH)/n (TPABr)=1:9~5:5，晶化时间24~72 h，晶化温度100～120 ℃。
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| 关 键 词： | EU-1 ZSM-5 复合分子筛 合成 |
| 收稿时间： | 2010-11-18 |
| 修稿时间： | 2011-2-14 |
SYNTHESIS AND CHARACTERIZATION OF EU-1/ZSM-5 COMPOSITE ZEOLITE |
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| Yan Ping,Ma Bo,Zhang Xiwen,Zhang Zhizhi.SYNTHESIS AND CHARACTERIZATION OF EU-1/ZSM-5 COMPOSITE ZEOLITE[J].Petroleum Processing and Petrochemicals,2011,42(6):17-22. |
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| Authors: | Yan Ping Ma Bo Zhang Xiwen Zhang Zhizhi |
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| Affiliation: | Yan Ping1,2,Ma Bo1,Zhang Xiwen 2,Zhang Zhizhi2(1.College of Petrochemical Engineering,Liaoning Shihua University,Fushun 113001,2.SINOPEC Fushun Research Institute of Petroleum & Petrochemicals) |
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| Abstract: | EU-1/ZSM-5 composite zeolite was synthesized with organic template(TPABr and TPAOH) and EU-1 zeolite was used as aluminum source.Assynthesized sample was characterized by XRD,FT-IR and SEM-EDS.XRD results showed that EU-1 and ZSM-5 were coexisted in the composite zeolite;its pattern was similar with that of the mechanical mixture of EU-1 and ZSM-5.FT-IR spectra showed that characteristic absorption bands of the composite zeolite shifted to higher wavenumber,compared with the mechanical mixture of EU-1 and Z... |
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| Keywords: | EU-1 ZSM-5 composite molecular sieve synthesis |
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