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One-pot sonochemical synthesis of dendron-stabilized gold nanoparticles as promising nano-hybrid with potential impact in biological application
Authors:Kwati Leonard  Hiroaki Okamura
Affiliation:
  • a Department of Chemistry and Bioscience, Graduate School of Science and Engineering, Kagoshima University, 1-21-35 Korimoto, Kagoshima 890-0065, Japan
  • b Sanme Chemical Co. Ltd., 10-3 Arashiyama, Saitama 255-0204, Japan
  • Abstract:Dihydroxy fatty acid-based (DF) dendron-stabilized gold nanoparticles (AuNps) were synthesized without adding any external reducing or stabilizing agent. Each DHA base dendron (G1, G2, or G3) possesses a single thiol at the focal point and free -OH groups at the other terminal and as a result can be used to reduce AuCl4 to Au0 and stabilize the nascent AuNps by the thiol group. The size and distribution of the AuNp produced can also be correlated with the rate of Au (III) reduction. TEM images vividly demonstrate the specific morphology of gold nanoparticles with different sizes and shapes obtained by using different generations of DF dendrons.
    Keywords:Dendron  Sonochemical synthesis  Gold nanoparticle  Third generation  TEM
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