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Facile synthesis of solution-disposable carbon nanotube-TiO2 hybrids in organic media
Authors:Xiumei Yan  Zhen Li  Jingchun Zhang
Affiliation:a Institute of Nanochemistry and Nanobiology, Shanghai University, Shanghai 201800, PR China
b School of Environment and Chemical Engineering, Shanghai University, Shanghai 201800, PR China
Abstract:Oleic acid-capped TiO2 nanoparticles (NPs) were directly grown on untreated multiwalled carbon nanotubes (MWCNTs) from a stable titanium carboxylate complex through a solvothermal aminolysis process in organic media. The shape of the TiO2 NPs loaded on the MWCNTs can be controlled from nanodots (∼ 3 nm in diameter) to nanorods (∼ 5 nm in diameter, 30-40 nm in length) by changing solvent components and by Co2+ doping. The resulting hybrids can be well dispersed in apolar organic solvents, which may provide possibilities for manipulating them in solutions for widespread applications.
Keywords:MWCNT-TiO2  Hybrids  Aminolysis  Nanomaterial  Nanocomposites
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