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Controlled synthesis and photoluminescence properties of hierarchical BaXO4 (X = Mo, W) nanostructures at room temperature
Authors:Lin Ma  Yuzeng Sun  Peng Gao  Yongkui Yin  Zengming Qin
Affiliation:a Key Laboratory of Physical and Chemical Materials, College of Heilongjiang Province, Harbin Normal University, Harbin 150025, PR China
b Key Laboratory of Superlight Materials and Surface Technology, Ministry of Education, Harbin Engineering University, Harbin 150001, PR China
Abstract:Controlled synthesis of hierarchical Barium molybdate (BaMoO4) nanostructures with different morphologies, such as peanut-like, cube-like and flower-like, was successfully achieved in aqueous solution at room temperature. The obtained products were characterized by a scanning electron microscope (SEM) and an X-ray power diffractometer (XRD). The morphologies of the obtained products were found to be greatly dependent on reaction time, EDTA concentration and the Ba2+]/MoO42−] ratio. This controllable method could be readily extended to produce hierarchical Barium tungstate (BaWO4) nanostructures with peanut-like, dumbbell-like, sphere-like and flower-like morphologies. The photoluminescence (PL) properties of the obtained BaMoO4 and BaWO4 nanostructures exhibited strong dependence on the morphologies and sizes, respectively.
Keywords:Hierarchical  Nanostructures  Controlled synthesis  BaMoO4  BaWO4
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