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Synthesis and molecular structure of the sodium arsanediyl zincate [(thf)Na]2[(EtZn)6(AsSiiPr3)4] |
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| Authors: | Matthias Westerhausen Gerhard Sapelza Peter Mayer |
| Affiliation: | aFriedrich-Schiller-Universität Jena, Institute of Inorganic and Analytical Chemistry, August-Bebel-Strasse 2, D-07743 Jena, Germany;bLudwig-Maximilians-Universität München, Department of Chemistry and Biochemistry, Butenandtstrasse 9, D-81377 Munich, Germany |
| Abstract: | The reaction of NaAs(H)SiiPr3 with ZnEt2 in the presence of additional triisopropylsilylarsane yields the heterobimetallic complex [(thf)Na]2 [(EtZn)6(AsSiiPr3)4] (1) in the shape of red prisms. The Na–As and Zn–As bond lengths show values of 301/309 pm and between 247 and 260 pm, respectively. |
| Keywords: | Sodium Zinc Arsanides Cage compounds Metallation reactions |
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