| 阴离子型微乳液的流变性 |
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| 引用本文： | 王红林,伍世英,王世权,李莹,陈宗淇. 阴离子型微乳液的流变性[J]. 青岛科技大学学报(自然科学版), 1994, 0(1) |
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| 作者姓名： | 王红林 伍世英 王世权 李莹 陈宗淇 |
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| 摘 要： | 对正十六烷、油酸钾、正己醇和水所形成的微乳液进行了研究，并对其流变性和机理作了探讨。结果表明：微乳液的粘度与水油比变化的机理可以用相转化来说明，即：以水为内相的球形→水的柱形→层状→油的柱形→水为外相的球形。层状结构区显示出有高粘度和异常流变性的特征，对此进行了讨论。
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| 关 键 词： | 微乳液；流变性 |
Rheological Properties of Anionic Microemulsion |
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| Wang Honglin,Wu Shiying,Wang Shiquan,Li Ying,Chen Zongoqi. Rheological Properties of Anionic Microemulsion[J]. Journal of Qingdao University of Science and Technology:Natutral Science Edition, 1994, 0(1) |
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| Authors: | Wang Honglin Wu Shiying Wang Shiquan Li Ying Chen Zongoqi |
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| Affiliation: | Department of Applied Chemistry |
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| Abstract: | Microemulsions which are optically transparent oilwater dispersions,were spontaneously produced upon mixing hexadecane,hexanol,potassium oleate,and water in specific proportions.The viscosity of microemulsions was measured for several water/oil ratios.The strikingoptical and wiscosity changes observed at specific water/oil ratios were in agreement with the proposed mechanism of phase inversion, namely, water spheres→water cyclinder→water lammellae→continuous water phase, for this system. In the lammellae region,the dispersion exhibited negative thixotropic and shear thick Properties. The bizarre rheological Properties exhibited bythe dispersion between water/oil ratios of 1 were explained in terms of ion-dipole associntion between oleate and hexanol molecules on adjacent droplets,which was investigated as a function ofpH,ratios of water,etc. |
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| Keywords: | microemulsion rheological property |
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