Application of Individual and Simultaneous Ozonation and Adsorption Processes in Batch and Fixed-Bed Reactors for Phenol Removal |
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Authors: | Selene Maria de Arruda Guelli Ulson de Souza Fernanda Batista de Souza Antônio Augusto Ulson de Souza |
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Affiliation: | Federal University of Santa Catarina, Chemical Engineering Department, Laboratory of Mass Transfer , 88040-900 , Florianópolis , Santa Catarina , Brazil |
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Abstract: | Ozonation, adsorption onto activated carbon and catalytic ozonation in batch and in a fixed-bed reactor for the removal/degradation of phenol and COD were investigated. In the case of batch ozonation the oxidation capacity was greater than 6.9 g of phenol/g O3, while the continuous ozonation system degraded 40% of the phenol and reduced the COD by 27.9%. The adsorption process provided over 99% removal for phenol and COD; however, it treated only 5 L compared with 17 L for the combined process, which also increased the total area and pore volume of the activated carbon, due to the formation of pores and a widening of micropores. |
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Keywords: | Ozone Adsorption Phenol COD Removal Degradation |
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