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棉织物聚合-交联体系的酯化反应动力学
引用本文:赵敏,周翔.棉织物聚合-交联体系的酯化反应动力学[J].印染助剂,2005,22(1):31-33,36.
作者姓名:赵敏  周翔
作者单位:东华大学,上海,200051
摘    要:研究了对马来酸/衣康酸及马来酸聚合-交联体系的酯化反应动力学,按照一级反应的设定,分别计算了MA/IA和MA聚合-交联整理体系酯化反应的反应速率常数、活化能、频率因子等动力学参数.所得动力学数据能够较好地解释整理品性能的差异.

关 键 词:马来酸  衣康酸  酯化  反应动力学
文章编号:1004-0439(2005)01-0031-03

Kinetics of the esterification of polymerization-crosslinking system on fabrics
ZHAO Min,ZHOU Xiang.Kinetics of the esterification of polymerization-crosslinking system on fabrics[J].Textile Auxiliaries,2005,22(1):31-33,36.
Authors:ZHAO Min  ZHOU Xiang
Abstract:The kinetics of the esterification of maleic acid (MA) / itaconic acid (IA) or maleic acid (MA) polymerization/crosslinking system was researched. The kinetic parameters such as reaction rate constants, activation energy, frequency factors etc. were separately calculated, on the basis of first order reaction, for the esterification of the MA / IA and MA polymerization/crosslinking finishing systems. The obtained kinetics data could well explain the differences of the properties of the finished fabrics.
Keywords:maleic acid  itaconic acid  esterification  reaction kinetics  
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