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Effect of treatment temperature on the early hydration characteristics of superplasticized silica fume blended cement pastes
Authors:M Heikal  MS Morsy
Affiliation:a Chemistry Department, Faculty of Science, Zagazig University, Benha Branch, Benha, Zagasig, Egypt
b Building Physics Department, Building Research Center, PO Box 1770, Cairo, Egypt
c Petrochemical Department, Egyptian Petroleum Research Institute, Cairo, Egypt
Abstract:In this investigation, two mixes were used: ordinary Portland cement (OPC) and a blended cement prepared with the partial substitution of OPC by 10 mass% silica fume (SF). The setting and hardening characteristics were monitored by the aid of electrical conductivity as a function of curing time. The shear stress and electrical conductivity were studied at different temperatures, namely, 20, 35, 45 and 55 °C. As the temperature increases, the shear stresses decrease with the increase of shear rate. The height of electrical conductivity peaks of superplasticized cement pastes increases due to the increase of the paste fluidity. In the presence of 1.0% polycarboxylate (PC), the electrical conductivity of cement pastes decreases from 1 to 28 days. PC retards the hydration of cement pastes. The presence of PC extended the setting times of cement pastes at 35 °C than at 20 °C due to the increase in the adsorption capacity at this temperature. PC extends the dormant stage of the hydration process and delays the onset of the accelerating stage, without affecting its rate.
Keywords:Blended cement  Silica fume  Temperature  Rheology  Electrical properties  Polymer
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