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ITO-free inverted polymer solar cells using a GZO cathode modified by ZnO
Authors:Soo-Ghang IhnKyung-Sik Shin  Mi-Jin JinXavier Bulliard  Sungyoung YunYeong Suk Choi  Yungi KimJong-Hwan Park  Myungsun SimMin Kim  Kilwon ChoTae Sang Kim  Dukhyun Choi  Jae-Young ChoiWoong Choi  Sang-Woo Kim
Affiliation:a Samsung Advanced Institute of Technology, Samsung Electronics, Yongin 446-712, Republic of Korea
b School of Advanced Materials Science and Engineering, Sungkyunkwan University, Suwon 440-746, Republic of Korea
c Department of Chemical Engineering, Pohang University of Science and Technology, Pohang 790-784, Republic of Korea
d SKKU Advanced Institute of Nanotechnology (SAINT) and Center for Human Interface Nanotechnology (HINT), Sungkyunkwan University, Suwon 440-746, Republic of Korea
Abstract:A gallium-doped ZnO (GZO) layer was investigated and compared with a conventional indium-tin-oxide (ITO) layer for use as a cathode in an inverted polymer solar cell based on poly(3-hexylthiophene) (P3HT):[6,6]-phenyl-C61 butyric acid methyl ester (PCBM) bulk heterojunctions (BHJ). By modifying the GZO cathode with a ZnO thin layer, a high power conversion efficiency (3.4%) comparable to that of an inverted solar cell employing the same P3HT:PCBM BHJ photoactive layer with a conventional ITO/ZnO cathode was achieved. This result indicates that GZO is a transparent electrode material that can potentially be used to replace high-cost ITO.
Keywords:Inverted polymer solar cell   Ga-doped ZnO   Transparent conducting oxide   ITO-free   Power conversion efficiency
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