Abstract: | Determination of the relative reaction rates of isomeric methyl octadecadienoates is possible by competitive reduction of a mixture containing an inactive diene and a radioactively labeled isomer. The hydrogenation rate of methylcis-9,cis-12-octadecadienoate with platinum and nickel catalysts is compared to the hydrogenation rate of each of several isomers of methyl octadecadienoate, and the relative rate of the competitive hydrogenations is calculated by a digital computer. Methylcis-9,cis-12 linoleate is reduced the most rapidly of all the dienes studied. The relative rates of the positional isomers tend to decrease with the increasing number of methylene groups between the double bonds, except when one of the double bonds is in the more reactive 15 position. Comparison of the geometric isomers shows thattrans,trans diene is hydrogenated at a slower rate thancis,cis linoleate. |