| 聚醚改性氨基硅油的合成及应用 |
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| 引用本文： | 史晨曦,李青,鲍利红.聚醚改性氨基硅油的合成及应用[J].北京服装学院学报,2011(2):36-44. |
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| 作者姓名： | 史晨曦 李青 鲍利红 |
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| 作者单位： | 北京服装学院材料科学与工程学院;北京市服装材料研究开发与评价重点实验室; |
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| 基金项目： | 北京市服装材料研发与评价重点实验室开放课题资助项目(2010ZK-11) |
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| 摘 要： | 以α,ω-二羟基聚二甲基硅氧烷（W S-62M）、N-β-氨乙基-γ-氨丙基甲基二甲氧基硅烷（DL-602）、单端环氧聚醚（X-O9）为主要原料,合成了一系列聚醚改性氨基聚硅氧烷,探讨了最佳改性条件,并考察了DL-602用量、n（X-O9）∶n（DL-602）对聚醚改性氨基硅油乳液性能及其应用性能的影响.结果表明：以异丙醇作溶剂,偶联剂用量为10%,n（X-O9）∶n（DL-602）=3∶1,80℃下反应4h为最佳反应条件;所制聚醚改性氨基硅油乳液稳定性好,用该乳液整理的织物其白度和亲水性均较氨基硅油有提高,与氨基硅油的摩擦系数相差不大,耐洗.
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| 关 键 词： | 聚醚改性氨基硅油 合成 乳液性能 应用性能 |
Synthesis and Application of Polyether-modified Amino-silicone |
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| SHI Chen-xi,LI Qing,BAO Li-hong.Synthesis and Application of Polyether-modified Amino-silicone[J].Journal of Beijing Institute of Clothing Technology(Nature Science Edition),2011(2):36-44. |
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| Authors: | SHI Chen-xi LI Qing BAO Li-hong |
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| Affiliation: | SHI Chen-xi1,LI Qing1,2,BAO Li-hong1,2**(1.School of Materials Science and Engineering,Beijing Institute of Fashion Technology,Beijing 100029,China,2.Beijing Key Laboratory of Clothing Materials R&D and Assessment,China) |
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| Abstract: | A series of polyether-modified amino-silicone were synthesized with α,ω-dihydroxypolydimethylsiloxane（WS-62M）,N-β-aminoethyl-γ-aminopropyl methyl dimethoxy siloxane（DL-602） and single-ended epoxy polyether as materials.The suitable modified conditions were obtained,and the influence of the mass percentage of DL-602 and the molar ratio of DL-602 to X-09 on the properties and application performance of polyether-modified amino-silicone solution was explored.Experiment results showed that the optimum experimental conditions were as the following： with isopropanol as solvent,when the dosage of DL-602 was 10 percent,the molar ration of DL-602 to X-O9 was 3 to 1,materials reacted at the temperature of 80 ℃ for 4 hours.The stability of the prepared polyether-modified amino-silicone emulsion was good.Compared with amino-silicone,the whiteness and hydrophilic of the fabric treated with this product were improved,there was little difference in the coefficient of friction and the fabric was washable. |
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| Keywords: | polyether-modified amino-silicone synthesis emulsion properties application performance |
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