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树枝状季铵盐型低聚表面活性剂对N80钢在盐酸溶液中的缓蚀性能
引用本文:李杰,陈巧梅,佟威,吴文祥. 树枝状季铵盐型低聚表面活性剂对N80钢在盐酸溶液中的缓蚀性能[J]. 材料保护, 2011, 44(4): 28-30,33,7
作者姓名:李杰  陈巧梅  佟威  吴文祥
作者单位:东北石油大学化学化工学院;东北石油大学石油工程学院;
基金项目:国家自然科学基金项目(51074033)资助
摘    要:开发具有新型结构的低聚表面活性剂,并进行应用基础研究,已成为应用化学领域研究的热点.以乙二胺、环氧氯丙烷、十二叔胺为原料,无水乙醇为溶剂,通过开环反应和季铵化反应合成了具有树枝状结构的季铵盐型低聚表面活性剂.应用静态挂片法、极化曲线、电化学阻抗谱研究了其在20%(质量分数)HCl溶液中对N80钢的缓蚀及吸附性能.结果表...

关 键 词:低聚表面活性剂  季铵盐  缓蚀  N80钢  盐酸体系  极化曲线  电化学阻抗  吸附

Corrosion Inhibition Performance of Dendritic Oligomeric Quaternary Ammonium Salt Surfactant for N80 Steel in Hydrochloric Acid
LI Jie,CHEN Qiao-mei,TONG Wei,WU Wen-xiang. Corrosion Inhibition Performance of Dendritic Oligomeric Quaternary Ammonium Salt Surfactant for N80 Steel in Hydrochloric Acid[J]. Journal of Materials Protection, 2011, 44(4): 28-30,33,7
Authors:LI Jie  CHEN Qiao-mei  TONG Wei  WU Wen-xiang
Affiliation:LI Jiea,CHEN Qiao-meia,TONG Weia,WU Wen-xiangb(a.College of Chemistry and Chemical Engineering,b.College of Petroleum Engineering,Northeast Petroleum University,Daqing 163318,China).
Abstract:A dendritic oligomeric quaternary ammonium salt surfactant was synthesized in absolute ethanol solvent via ring-opening reaction and quaternization reaction of starting materials(ethylenediamine,epichlorohydrin and dodecyl dimethyl amine).Performance of resultant oligomeric surfactant for N80 steel in 20% HCl solution was investigated based on weight-loss test and measurement of polarization curve and electrochemical impedance spectra.Results show that as-synthesized oligomeric surfactant has good corrosion...
Keywords:oligomeric surfactant  quaternary ammonium salt  corrosion inhibition  N80 steel  hydrochloric acid  polarization curve  electrochemical impedance spectra  adsorption  
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