Preliminary Studies on Furfural Production from Lignocellulosics |
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| Authors: | Bianca Moreira Barbosa Jorge Luiz Colodette Dalton Longue Júnior Fernando José Borges Gomes Daniela Correia Martino |
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| Affiliation: | 1. Department of Chemistry , Federal University of Vi?osa , Vi?osa , Minas Gerais , Brazil;2. Department of Forestry Engineering , Federal University of Vi?osa , Vi?osa , Minas Gerais , Brazil |
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| Abstract: | This study focused on the production of furfural from agricultural and industrial biomass residues by a hydrodistillation process. Corncobs, sugarcane bagasse, and eucalypt wood were treated with sulfuric, hydrochloric, and phosphoric acids as catalysts, with different acid concentrations (1.5 to 5.2 mol.L ?1). In addition, the eucalypt liquor from the auto-hydrolysis, kraft-dissolving pulp production process was also investigated as a source of furfural, using sulfuric and hydrochloric acids as a catalyst (0.9 and 3.9 mol.L ?1) . Furfural yields of 30.2, 25.8, and 13.9% were achieved for corncob, sugarcane bagasse, and eucalypt wood, respectively, on the basis of biomass dry weight. The efficiency of conversion from pentose to furfural using eucalypt liquor from the auto-hydrolysis kraft process was 71.5% using HCl 3.9 mol.L ?1 . Due to the presence of a high amount of pentose, corncob produced the highest amount of furfural, followed by sugarcane bagasse and then eucalypt wood. |
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| Keywords: | Furfural mineral acids auto-hydrolysis hemicelluloses dissolving pulp production |
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