牛磺酸的溶解特性及其介稳区性质研究 |
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引用本文: | 刘祎,程敬华,周玉新. 牛磺酸的溶解特性及其介稳区性质研究[J]. 河南化工, 2013, 0(16): 29-32 |
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作者姓名: | 刘祎 程敬华 周玉新 |
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作者单位: | 武汉工程大学化工与制药学院绿色化工过程省部共建教育部重点实验室,湖北武汉430073 |
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摘 要: | 通过测定牛磺酸的溶解度和过饱和度研究了牛磺酸的介稳区性质,并绘制了介稳区曲线,得到了牛磺酸的介稳区宽度.同时,还研究了降温速度和搅拌速度对介稳区宽度的影响,并推算出牛磺酸的成核级数.结果表明:牛磺酸在水溶液中的溶解度随着温度的升高而显著增大;其介稳区宽度随着饱和温度的增大而变窄;降温速度越快,介稳区宽度越宽;搅拌速度越快,介稳区宽度越窄.受降温速度和搅拌速度影响的成核级数与饱和温度几乎无关,成核级数分别为1.82和2.04.
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关 键 词: | 牛磺酸 介稳区 结晶 |
Study on Dissolution Characteristics of Taurine and Meta-stable Zone Property |
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Affiliation: | LIU Yi , CHENG Jing -hua , ZHOU Yu -xin ( School of Chemical Engineering and Pharmacy , Key Laboratory for Green Chemical Process of Ministry of Education , Wuhan Institute of Technology , Wuhan 430073 , China) |
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Abstract: | The meta - stable zone property of taurine are investigated, the solubility and the super - satura- tion of taurine in aqueous solution are measured, and then the meta - stable zone width is determined by drawing the curve of meta - stable zone. In addition, the effects of stirring rate and cooling rate on the me- ta- stable zone width are studied in aqueous solution, and the nucleation progression of taurine is esti- mated. Experimental result shows that increasing the temperature the solubility of taurine in aqueous solu- tion increases distinctly. With the increasing of the saturation temperature, the meta - stable zone width narrows. The faster cooling rate is, the wider meta - stable zone width will be. The faster stirring rate is, the narrower meta - stable zone width will be. The nucleation progression, which is affected by the maxi- mum super - saturation and stirring rate, had no relationship with saturation temperature, and they were 1. 82 and 2.04 respectively. |
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Keywords: | :taurine meta- stable zone crystallization |
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