Design and application of a multifunctional reactive dye capable of high fixation efficiency on cellulose |
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Authors: | K F Morris D M Lewis P J Broadbent |
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Affiliation: | Department of Colour and Polymer Chemistry, University of Leeds, Leeds LS2 9JT, UK Email: |
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Abstract: | A polyfunctional reactive dye containing two dichloro- s -triazine residues linked through aliphatic amino groups via a third triazine system to the chromophoric residue has been prepared. The dye was synthesised stepwise from a specially synthesised 2,4-dichloro- s -triazine dyes. The first step is the reaction of both carbon–chlorine sites in the 'parent' dye with 2 mol ethylenediamine under selected conditions of pH and temperature; these conditions ensure that only one of the amino groups in the ethylenediamine will react to give the bis-2,4-aminoethyleneaminotriazine dye. The second step is the condensation of 2 mol cyanuric chloride with the two pendant primary amino groups. The alkylamino-linked dichloro- s -triazine dyes show very different dyeing properties when compared with those shown by the parent dichloro- s -triazine dye, which has the reactive group linked directly into the aromatic chromophore; in particular, the new dyes have high fixation efficiencies when dyed on cotton at 50 °C and the dye–fibre bond stability to boiling acidic conditions is very good. |
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