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黄酒生产中氨基甲酸乙酯的监测与控制
引用本文:巫景铭,洪瑞泽,马丽辉,许和强.黄酒生产中氨基甲酸乙酯的监测与控制[J].酿酒,2011,38(3):64-67.
作者姓名:巫景铭  洪瑞泽  马丽辉  许和强
作者单位:广东省酒类检测中心,广东,广州,510410
摘    要:氨基甲酸乙酯(EC)是一种基因致癌物,黄酒中含量较高。应用SPE结合GC/MS方法对广东黄酒生产过程中产生的氨基甲酸乙酯进行全程监测分析,在水和糖化液里未能检出EC,米酒、发酵液、煎酒液和成品中EC平均含量分别为8.2μg/kg、7.9μg/kg、21.6μg/kg、52.7μg/kg,其中70%的EC是在煎酒和贮存过程中产生。需加强对黄酒生产工艺和贮存条件的管理和改进,以减少EC的产生,确保广东地产黄酒的竞争性及安全性。

关 键 词:氨基甲酸乙酯  GC/MS  固相萃取  黄酒

Determination and Control of Ethyl Carbamate in the production of Rice Wine
WU Jing-ming,HONG Rui-ze,MA Li-hui,XU He-qiang.Determination and Control of Ethyl Carbamate in the production of Rice Wine[J].Liquor Making,2011,38(3):64-67.
Authors:WU Jing-ming  HONG Rui-ze  MA Li-hui  XU He-qiang
Affiliation:WU Jing-ming,HONG Rui-ze,MA Li-hui,XU He-qiang(Guangdong provincial wine testing center,Guangzhou,Guangdong 510410,China)
Abstract:Ethyl carbamate(EC) is a carcinogen which existed in rice wine.Base on a monitoring research of using SPE-GC/MS to determine EC content of rice wine producing in Guangdong,the content of EC in spirit,fermentation liquor,fried liquor and finished rice wine were 8.2μg/kg,7.9μg/kg,21.6μg/kg,52.7μg/kg,while in water or diastatic liquid were not detected.It was found that 85% of EC were brought from frying and storing process.To ensure the competitiveness and security of Guangdong rice wine,producers need to improve the process and storage conditions to reduce the production of EC.
Keywords:Ethyl carbamate  Gas Chromatography/ Mass Spectrometry  solid-phase extraction  rice wine  
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