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Transport Properties of K_xV_2O_5·nH_2O Nanocrystalline Films
作者姓名:A.A.Bahgat  H.A.Mady  A.S.Abdel Moghny  A.S.Abd-Rabo  Samia E.Negm
作者单位:Department of Physics;Faculty of Science;Al-Azhar University;
摘    要:Five different compositions of K x V 2 O 5 ·nH 2 O(where x=0.00,0.0017,0.0049,0.0064 and 0.0091 mol) were prepared by the sol-gel process.Electrical conductivity and thermoelectric power were measured parallel to the substrate surface in the temperature range of 300-480 K.The electrical conductivity showed that all samples were semiconductors and that conductivity increased with increasing K content.The conductivity of the present system was primarily determined by hopping carrier mobility.The carrier density was evaluated as well.The conduction was confirmed to obey non-adiabatic small polaron hopping.The thermoelectric power or Seebeck effect,increased with increasing K ions content.The results obtained indicated that an n-type semiconducting behavior within the temperature range was investigated.

关 键 词:纳米晶薄膜  n型半导体  属性  传输  载流子迁移率  温度范围  载流子密度  塞贝克效应

Transport Properties of KxV2O5·nH2O Nanocrystalline Films
A.A.Bahgat,H.A.Mady,A.S.Abdel Moghny,A.S.Abd-Rabo,Samia E.Negm.Transport Properties of KxV2O5·nH2O Nanocrystalline Films[J].Journal of Materials Science & Technology,2011(10):865-872.
Authors:AABahgat  HAMady  ASAbdel Moghny  ASAbd-Rabo  Samia ENegm
Affiliation:A.A.Bahgat,H.A.Mady,A.S.Abdel Moghny,A.S.Abd-Rabo and Samia E.Negm Department of Physics,Faculty of Science,Al-Azhar University,Nasr City 11884,Cairo,Egypt
Abstract:Five different compositions of KxV2O5 ·nH2O(where x=0.00,0.0017,0.0049,0.0064 and 0.0091 mol) were prepared by the sol-gel process.Electrical conductivity and thermoelectric power were measured parallel to the substrate surface in the temperature range of 300-480 K.The electrical conductivity showed that all samples were semiconductors and that conductivity increased with increasing K content.The conductivity of the present system was primarily determined by hopping carrier mobility.The carrier density was evaluated as well.The conduction was confirmed to obey non-adiabatic small polaron hopping.The thermoelectric power or Seebeck effect,increased with increasing K ions content.The results obtained indicated that an n-type semiconducting behavior within the temperature range was investigated.
Keywords:Vanadium pentoxide xerogel  Nanocrystalline film  Electrical conductivity  Small polaron hopping  
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