| 多孔银钌合金催化剂的制备、表征和性能研究 |
| |
| 引用本文： | 郭荣贵,蒋文全,傅钟臻,于丽敏,李涛,杨慧. 多孔银钌合金催化剂的制备、表征和性能研究[J]. 材料导报, 2011, 0(Z1): 88-90,106 |
| |
| 作者姓名： | 郭荣贵 蒋文全 傅钟臻 于丽敏 李涛 杨慧 |
| |
| 作者单位： | 北京有色金属研究总院分析测试研究所; |
| |
| 摘 要： | 以葡聚糖为软模板制备了多孔AgRu合金催化剂,利用X射线衍射仪和扫描电镜仪对其结构和形貌进行表征,并研究了其催化性能。结果表明,6种催化剂的催化产氢活性次序为Ag9.2Ru>Ag3.6Ru>Ag4.0Ru>Ag13.5-Ru>Ag21.3Ru>Ag22.4Ru。银钌原子比和催化剂形貌共同影响催化剂性能。其中选用Ag9.2 Ru催化剂考察了NaBH4和NaOH的质量分数对产氢速率的影响,研究结果表明,随NaBH4和NaOH质量分数的增加,催化产氢速率降低。
|
| 关 键 词： | 银钌合金 硼氢化钠 催化水解 |
Preparation,Characterization and Performance of Porous Ag-Ru Alloy Catalysts |
| |
| GUO Ronggui,JIANG Wenquan,FU Zhongzhen,YU Limin,LI Tao,YANG Hui. Preparation,Characterization and Performance of Porous Ag-Ru Alloy Catalysts[J]. Materials Review, 2011, 0(Z1): 88-90,106 |
| |
| Authors: | GUO Ronggui JIANG Wenquan FU Zhongzhen YU Limin LI Tao YANG Hui |
| |
| Affiliation: | GUO Ronggui,JIANG Wenquan,FU Zhongzhen,YU Limin,LI Tao,YANG Hui (General Research Institute for Nonferrous Metals,Beijing 100088) |
| |
| Abstract: | Porous Ag-Ru alloy catalysts were synthesized with dextran as soft template.The characterizations of catalysts were studied by XRD and SEM,and the activity on hydrogen generation rate decreased in the following order Ag_(9.2)Ru>Ag_(3.6)Ru>Ag_(4.0)Ru>Ag_(13.5)Ru>Ag_(21.3)Ru>Ag_(22.4)Ru.The performance of the catalysts was influenced by the atom ratio of Ag to Ru and catalyst form.The influences of concentration of NaBH_4 and NaOH on hydrogen generation rate with Ag_(9.2)Ru catalyst were studied,indicating th... |
| |
| Keywords: | Ag-Ru alloys sodium borohydride catalytic hydrolysis |
| 本文献已被 CNKI 等数据库收录！ |
|
