| CO与烯烃共聚反应钯系催化剂的研究进展 |
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| 引用本文： | 丁广磊,贾庆明,陕绍云,李丹.CO与烯烃共聚反应钯系催化剂的研究进展[J].材料导报,2011(Z1). |
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| 作者姓名： | 丁广磊 贾庆明 陕绍云 李丹 |
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| 作者单位： | 昆明理工大学化学工程学院; |
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| 基金项目： | 国家自然科学基金(50963004); 云南省中青年学术技术带头人后备人才项目(2009CI029) |
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| 摘 要： | 钯系催化剂具有较高的催化活性和选择性,一直是CO与烯烃共聚反应制备聚酮研究较多的催化体系。但由于其价格较高,严重制约了CO与烯烃共聚制备聚酮的工业化进程。系统分析了近几年来钯系催化剂的研究进展,包括钯种类、配体类型、钯的负载方式及反应介质的应用等。以期为制备新型、高效的钯催化剂提供思路,推动CO与烯烃共聚反应制备聚酮的工业化发展。
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| 关 键 词： | CO 聚酮 钯系催化剂 研究进展 |
Research Progress of Palladium Catalyst for Copolymerization of CO and Olefin |
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| DING Guanglei,JIA Qingming,SHAN Shaoyun,LI Dan.Research Progress of Palladium Catalyst for Copolymerization of CO and Olefin[J].Materials Review,2011(Z1). |
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| Authors: | DING Guanglei JIA Qingming SHAN Shaoyun LI Dan |
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| Affiliation: | DING Guanglei,JIA Qingming,SHAN Shaoyun,LI Dan (Faculty of Chemical Engineering,Kunming University of Science and Technology,Kunming 650224) |
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| Abstract: | As the palladium catalyst has high catalytic activity and selectivity,it has been extensively studied, used as catalytic system for copolymerization reaction of CO and olefia However,high price of palladium has seriously restricted the industrialization process of polyketones prepared by copolymerization of CO and olefia Research progress of the Pd catalysts,including palladium species,ligand type,load mode and the application of reaction medium were systematically analyzed.This research progress expects fo... |
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| Keywords: | CO polyketone palladium catalyst research progress |
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