| 纤维素膦-钯催化剂上制备2-环戊基环戊酮的研究 |
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| 引用本文： | 许绍东.纤维素膦-钯催化剂上制备2-环戊基环戊酮的研究[J].辽阳石油化工高等专科学校学报,1999(4). |
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| 作者姓名： | 许绍东 |
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| 作者单位： | 辽阳石油化工高等专科学校基础部!辽阳，111003 |
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| 摘 要： | 用纤维素二苯基膦与PdC12制备了纤维素膦-钯催化剂，在纤维素膦-钯催化剂上对空间位阻大的2-亚环戊基环戊酮的烯键催化氢化进行了研究．利用气相色谱法测定了催化氢化反应的反应程度及选择性．探讨了2-亚环戊基环戊酮在纤维素膦-钯催化剂上合成2-亚环戊基环戊酮的反应机理．
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| 关 键 词： | 2-亚环戊基环戊酮 2-环戊基环戊酮 催化氢化 选择性 气相色谱法 测定 |
Preparation of Cyclopentyl Cyclopentanone on Catalyst of Palladium Complexes with Cellulose Diphenyl Phasphine |
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| Xu Shaodong.Preparation of Cyclopentyl Cyclopentanone on Catalyst of Palladium Complexes with Cellulose Diphenyl Phasphine[J].Journal of Liaoyang Petrochemical College,1999(4). |
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| Authors: | Xu Shaodong |
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| Abstract: | Catalyst of palladium complexes with cellulose diphenyl phasphine had been prepared Bypalladium chloride and cellulose diphenyl phasphine. Hydrogenation of 2- cyclopentylidene cyclopentanone that is stereoacopically defined had been studied. Reactivity and selectivity of hydrogenation reaction were determined by GC. The mechanism of hydrogenation of cyclopentylidene cyclopentanone were dilcussed. |
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| Keywords: | Cyclopentylidene cyclopentanone Cyclopentylcy clopentanone Hydrogenation Selectivity |
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