Phase diagram and thermodynamic properties of phases in the In-Te system |
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| Authors: | V P Zlomanov M S Sheiman and B Legendre |
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| Affiliation: | (1) Department of Chemistry, Moscow State University, 119899 Moscow, Russia;(2) Chemical Institute, Nizhnii Novgorod State University, 603600 Nizhnii, Novgorod, Russia;(3) Laboratoire de Physique Minerale, Faculte de Pharmacie, Rue J.B. Clement, 92290 Chatenay-Malabry, France |
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| Abstract: | The In-Te phase diagram was refined in the composition range 0 to 71.77 at.% Te; the phases In4Te3, InTe, In2Te3, and In2Te5 were found to exist. Vaporization of In2Te3 and InTe was studied by the mass spectrometric method and the p
Te
2
-T diagram was constructed. The standard molar enthalpies of formation of mentioned compounds were determined by direct synthesis
calorimetry. The heat capacity of the solid In2Te3 was measured in a vacuum adiabatic calorimeter at 5 to 310 K, and the H
o(T)-H
o(0), S
T
, and G
o(T)-H
o(0) functions were calculated. |
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