| 2-羟基-4-氧杂三环[4,2,1,03,7]-5-壬酮的合成与表征 |
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| 引用本文： | 杨振强,司江坤,蒋卫鹏,李江涛,杨瑞娜.2-羟基-4-氧杂三环[4,2,1,03,7]-5-壬酮的合成与表征[J].化工技术与开发,2012(3):1-2,12. |
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| 作者姓名： | 杨振强 司江坤 蒋卫鹏 李江涛 杨瑞娜 |
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| 作者单位： | 河南省科学院化学研究所;郑州轻工业学院应用化学系 |
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| 基金项目： | 河南省杰出人才创新基金(094200510014) |
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| 摘 要： | 2-羟基-4-氧杂三环4,2,1,03,7]-5-壬酮是光电材料的重要中间体,本文以丙烯酸和环戊二烯为原料,经Diels-Alder和氧化合成目标化合物,并通过1H NMR、13C NMR、MS和IR表征确定了5-降冰片烯-2-甲酸和目标化合物结构。
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| 关 键 词： | 内型5-降冰片烯-2-甲酸 2-羟基-4-氧杂三环[4 2 1 03 7]-5-壬酮 环戊二烯 |
Synthesis and Characterization of 2-Hydroxy-4-oxatricyclo [4,2,1,03,7] nonan-5-one |
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| YANG Zhen-qiang,SI Jiang-kun,JIANG Wei-peng,LI Jiang-tao,YANG Rui-na.Synthesis and Characterization of 2-Hydroxy-4-oxatricyclo [4,2,1,03,7] nonan-5-one[J].Technology & Development of Chemical Industry,2012(3):1-2,12. |
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| Authors: | YANG Zhen-qiang SI Jiang-kun JIANG Wei-peng LI Jiang-tao YANG Rui-na |
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| Affiliation: | 1(1.Institute of Chemistry Henan Academy of Sciences,Zhengzhou 450002,China; 2.Department of Applied Chemistry,Zhengzhou University of Light Industry,Zhengzhou 450002,China) |
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| Abstract: | 2-Hydroxy-4-oxatricyclo4,2,1,03,7]nonan-5-one was known as an important intermediate of photoelectric material,and was synthesized by the Diels-Alder addition reaction and oxidizing reaction from the crylic acid and cyclopentadiene.The structure of 5-norbornene-2-carboxylic acid and the title compound were characterized by 1H NMR,13C NMR,IR and MS. |
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| Keywords: | 2-hydroxy-4-oxatricyclo[4 2 1 03 7] nonan-5-one endo-5-norbornene-2-carboxylic acid cyclopentadiene |
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