Copolymerization of Norbornene and Styrene Catalyzed by a Series of Bis(β-ketoamine) Nickel(II) Complexes in the Presence of Methylaluminoxane

Summary Random copolymerization of norbornene with styrene was studied by using a series of late metal catalysts/MAO. The precatalysts used here are nickel complexes with b-ketoamine ligands based on pyrazolone derivatives. The copolymers obtained here suggest that only one type of active species is present. Copolymers were characterized by ¹³C NMR, Gel permeation chromatography (GPC), thermogravimetric analysis (TGA) and FT-IR spectra. The analyses of the product by ¹H NMR and ¹³C NMR spectra gave the verification of “true” random vinyl addition copolymer. Varying the monomer feed ratio controlled the composition of the copolymers. A copolymerization reactivity ratio (r_NBE = 20.35 and r_Sty = 0.027) indicates a much higher reactivity of norbornene, which suggests a coordination polymerization mechanism. The solubility and processability of the copolymers are improved relative to polynorbornene and the thermostability of the copolymers is improved relative to polystyrene.