On-line control of processing atmospheres for proper sintering of oxidation-sensitive PM steels |
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Authors: | E Hryha E Dudrova L Nyborg |
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Affiliation: | a Department of Materials and Manufacturing Technology, Chalmers University of Technology, Rännvägen 2A, SE - 412 96 Gothenburg, Sweden b Institute of Materials Research, Slovak Academy of Science, Watsonova 47, 043 53 Košice, Slovakia |
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Abstract: | Changes of atmosphere composition during sintering of water atomized powder prealloyed with Mn and Cr (up to 2% of both) were studied. Increasing sensitivity to atmosphere purity with increasing alloying elements content was registered. Continuous monitoring of sintering atmosphere composition (CO/CO2/H2O) indicates three critical stages during the heating up to final sintering temperature: the importance of rapid atmosphere purification after lubricant decomposition and removal; the reduction of the iron oxide layer by hydrogen at temperatures up to ∼500 °C and by carbon at temperatures around ∼720 °C; the reduction of the spinel oxides on the powder surface at above 900 °C and further reduction of thermodynamically stable surface oxides and mixed internal oxides close to the sintering temperature. The measured ratio of CO/CO2 indicates favorable thermodynamic conditions for reduction of stable oxides as (Cr,Mn)xOy close to sintering temperature (1120 °C) for the applied sintering conditions. The experimental results were confirmed by modeling the metal-gas interactions using the thermodynamic/thermochemical softwares ThermoCalc and HSC Chemistry. The modeling indicates the significance of maintaining a sintering atmosphere with high reducing potential during heating stage for minimizing oxidation before high-temperature carbothermal reduction starts. |
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Keywords: | Prealloyed powder Sintering Processing atmosphere Atmosphere monitoring Oxide reduction Carbothermal reduction |
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