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Tunable light emission and similarities with garnet structure of Ce-doped LSCAS glass for white-light devices
Authors:L.H.C. Andrade  S.M. LimaM.L. Baesso  A. NovatskiJ.H. Rohling  Y. GuyotG. Boulon
Affiliation:a Grupo de Espectroscopia Óptica e Fototérmica, Universidade Estadual de Mato Grosso do Sul - UEMS, C.P. 351, Dourados, MS, Brazil
b Grupo de Estudos de Fenômenos Fototérmicos, Departamento de Física, Universidade Estadual de Maringá, Av. Colombo 5790, 87020-900 Maringá, PR, Brazil
c Laboratoire de Physico-Chimie des Matériaux Luminescents, Université Claude Bernard Lyon 1, UMR 5620 CNRS, 69622 Villeurbanne, France
Abstract:In this paper, we report results concerning tunable light emission and color temperature in cerium-doped low-silica-calcium-alumino-silicate (LSCAS) glass for smart white-light devices. Spectroscopic results, analyzed using the CIE 1931 x-y chromatic diagram, show that this glass presents two broad emission bands centered at 475 and 540 nm, whose intensities can be tuned by the excitation wavelength. Moreover, the same emission can be achieved from a color temperature range from 3200 to 10,000 K, with a color-rendering index (CRI) of around 75% obtained by changing the optical path length of the sample. Our new phosphor LSCAS glass, which is a unique system that exhibits tunable yellow emission, combines all qualities for white-light devices.
Keywords:Ce-doped LSCAS glass   Smart white-light   Phosphors   Amorphous materials   Optical materials   Optical properties
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