Synthesis of Y‐shaped poly(N,N‐dimethylamino‐2‐ethyl methacrylate) and poly(trimethylene carbonate) from a new heterofunctional initiator |
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| Authors: | Huaihong Zhang Baiwang Sun Yaoqiang Chen Jianli Wang |
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| Affiliation: | 1. School of Chemistry and Biology, Yancheng Institute of Technology, Yancheng 224007, China;2. College of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, China;3. College of Chemistry, Sichuan University, Chengdu 610064, China |
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| Abstract: | A new amphiphilic Y‐shaped copolymer, comprised of hydrophobic Poly(trimethylene carbonate) (PTMC) and hydrophilic Poly(N,N‐dimethylamino‐2‐ethyl methacrylate) (PDMAEMA), was designed and synthesized by a combination of atom transfer radical polymerization (ATRP) and ring‐opening polymerization (ROP) using a new heterofunctional initiator, Br‐Init‐(OH)2, bearing one initiation site for ATRP and two for ROP. At first, a new trifunctional core molecule bearing hydroxyl group and bromine moieties, Br‐Init‐(OH)2, was synthesized via protection followed by esterification reaction of 5‐ethyl‐5‐hydroxymethyl‐2,2‐dimethyl‐1,3‐dioxane with 2‐bromoisobutyryl bromide and deprotection. In the presence of trifunctional core molecule, Br‐Init‐(OH)2, target Y‐shaped miktoarm star copolymers, (PTMC)2‐ b‐PDMAEMA, were successfully synthesized by sequence conducting the ROP of TMC and ATRP of DMAEMA. The Y‐shaped copolymers were characterized by 1H NMR and GPC measurements. Subsequently, the self‐assembly behavior of these copolymers was investigated by dynamic light scattering method and transmission electron microscopy, which indicated that these amphiphilic Y‐shaped copolymers can self‐assemble into micelles and possess distinct pH‐dependent size in aqueous milieu. The results indicate that the amphiphilic Y‐shaped copolymers had the pH‐responsive properties similar to the expected PDMAEMA. POLYM. ENG. SCI., 2011. © 2011 Society of Plastics Engineers |
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