Efficiency of 4,4′‐bis(N,N‐diethylamino) benzophenone for the polymerization of dimethacrylate resins in thick sections |
| |
| Authors: | Walter F Schroeder Silvana L Asmussen Wayne D Cook Claudia I Vallo |
| |
| Affiliation: | 1. Institute of Materials Science and Technology (INTEMA), Universidad Nacional de Mar del Plata–National Research Council (CONICET), Av. Juan B Justo 4302, 7600 Mar del Plata, Argentina;2. Department of Materials Engineering, Monash University, Melbourne, Victoria 3800, Australia |
| |
| Abstract: | The efficiency of 4,4′‐bis(N,N‐diethylamino)benzophenone (DEABP) for the polymerization of dimethacrylate monomers in thick sections ( 1 – 2 mm) was studied. DEABP (λmax = 365 nm) represents a complete initiating system as it contains both ketone and amine functional groups. During irradiation, DEABP photobleaches at a fast rate causing deeper penetration of light through the underlying layers, but the photoinitiation efficiency (rate of polymerization per photon absorption rate) is relatively poor. As a result, irradiation of methacrylate monomers at 365 nm results in a slow average polymerization rate and a reduced monomer conversion for thick sections due to the light attenuation caused by the high absorptivity of DEABP and photolysis products. These results highlight the inherent interlinking of light attenuation and photobleaching rate in polymerization of thick sections. Copyright © 2011 Society of Chemical Industry |
| |
| Keywords: | frontal photopolymerization benzophenone dimethacrylate photobleaching |
|
|
