Stabilizations of molecular structures and mechanical properties of PVC and wood/PVC composites by Tinuvin and TiO2 stabilizers |
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| Authors: | Kantima Chaochanchaikul Narongrit Sombatsompop |
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| Affiliation: | 1. Polymer PROcessing and Flow (P‐PROF) Group, School of Energy, Environment and Materials, King Mongkut's University of Technology Thonburi (KMUTT), Thongkru, Bangmod, Bangkok 10140, Thailand;2. Email:narongrit.som@kmutt. ac.th |
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| Abstract: | Three different UV stabilizers, 2‐(2H‐benzotriazol‐2‐yl)‐4,6‐ditertpentylphenol (Tinuvin XT833), 2‐(2H‐benzotriazol‐2‐yl)‐p‐cresol (Tinuvin P), or rutile–titanium dioxide (TiO2) were incorporated into poly(vinyl chloride) (PVC) and wood/PVC (WPVC) composite, and mechanical and physical properties and photostabilities were monitored. The polyene and carbonyl sequences of PVC increased with UV weathering time and with presence of wood flour. The yellowness index increased because of polyene and carbonyl productions, whereas the brightness increased because of the photobleaching of lignin in wood. The photostabilities of PVC and WPVC could be improved through the use of UV stabilizers. Tinuvin P was recommended in this work as the most effective stabilizer for PVC and WPVC composites. The stabilization effect was interfered by presence of wood particles. The mechanical property changes corresponded well to the structural changes under UV for neat PVC. For WPVC composites, the presence of wood particles played more significant effect on the mechanical properties during UV aging than the UV stabilizer. POLYM. ENG. SCI., 2011. © 2011 Society of Plastics Engineers |
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